保护基缩略语全名大全.docx

1、保护基缩略语全名大全意：在某些例子中，不同的缩略语代表相同的保护基，或者相同的缩略语代表不同的保护基；列表根据protective groups in organic synthesis third edition整理。整理过程中可能有疏漏和错误，欢迎大家指出，以便完善。全名中的alpha代表 此外欢迎大家在回复中补充新的缩略语。补充格式：缩略语 全名ABO 2,7,8-trioxabicyclo3.2.1octylAC acetylACBZ 4-azidobenzyloxycarbonylAcHmb 2-acetoxy-4-methoxybenzylAcm acetamidomethylAd

2、 1-adamantylAdoc 1-adamantyloxycarbonylAdpoc 1-(1-adamantyl)-1-methylethoxycarbonylAlloc or AOC allyloxycarbonylAls allylsulfonylAMB 2-(acetoxymethyl)benzoylAN 4-methoxyphenyl or anisylAnpe 2-(4-acetyl-2-nitrophenyl)ethylAOC or Alloc allyloxycarbonylp-AOM p-anisyloxymethyl or (4-methoxyphenoxy)methy

3、lAzb p-azidobenzylBam benzamidomethylBBA butane-2,3-bisacetalBDMS biphenyldimethylsilylBdt 1,3-benzodithiolan-2-ylBetsyl or Bts benzothiazole-2-sulfonylBic 5-benzisoxazolylmethoxycarbonylBim 5-benzisoazolylmethyleneBimoc benzfinden-3-ylmethoxycarbonylBIPSOP N-2,5-bis(triisopropylsiloxy)pyrrolyl BMB

4、o-(benzoyloxymethyl)benzoylBmpc 2,4-dimethylthiophenoxycarbonylBmpm bis(4-methoxyphenyl)- 1-pyrenylmethylBn benzylBnpeoc 2,2-bis(4-nitrophenyl)ethoxycarbonylBOC t-butoxycarbonylBOM benzyloxymethylBpoc 1-methyl-1-(4-biphenyl)ethoxycarbonylBSB benzoSTABASEBsmoc 1,1-dioxobenzobthiophene-2-ylmethoxycarb

5、onylBts or Betsy1 benzothiazole-2-sulfonylBSE 2-t-butylsulfonylethylBum t-butoxymethylt-Bumeoc 1-(3,5-di-t-butylphenyl)-1-methylethoxycarbonylBus t-butylsulfonylBz benzoylCAEB 2-(2-chloroacetoxy)ethylbenzoylCam carboxamidomethylCAMB 2-(chloroacetoxymethyl)benzoylCbz or Z benzyloxycarbonylCDA cyclohe

6、xane-1,2-diacetalCDM 2-cyano-1,l-dimethylethylCE or Cne 2-cyanoethylCee 1-(2-chloroethoxy)ethylcHex cyclohexylClimoc 2-chloro-3-indenylmethoxycarbonylCms carboxymethylsulfenylCne or CE 2-cyanoethylCoc cinnamyloxycarbonylCpeoc 2-(cyano-1-phenyl)ethoxycarbonylCPTr 4,4,4-tris(4,5-dichlorophthalimido)tr

7、iphenylmethylCTMP 1-(2-chloro-4-methyl)phenyl-4-methoxypiperidin-4-ylCys cysteineDAM di-p-anisylmethyl or bis(4-methoxyphenyl)methylDATE 1,1-di-p-anisyl-2,2,2-trichloroethylDB-t-BOC 1,1-dimethyl-2,2-dibromoethoxycarbonylDBD-Tmoc 2,7-di-t-butyl9-(10, 10-dioxo-10,1O,1O,10-tetra=hydrothioxanthyl)DBS me

8、thoxycarbonylDde dibenzosuberylDdz 2-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylDEM 1-methyl-1-(3,5-dimethoxyphenyl)ethoxycarbonylDEIPS diethoxymethylDesyl diethylisopropylsilylDim 2-oxo-1,2-diphenylethylDmab 1,3-dithianyl-2-methylDMB 4-(N-1-(4,4-dimethyl-2,6-dioxocyclohexylidene)-3-methylbutylamin

9、o)benzylDmb “3,5-dimethoxybenzoin”DMIPS 2,4-dimethoxybenzylDmoc dimethylisopropylsilylDmp dithianylmethoxycarbonylDmp 2,4-dimethyl-3-pentylDMPM dimethylphosphinylDMT or DMTr 3,4-dimethoxybenzylDMTr or DMT di(p-methoxyphenyl)phenylmethyl or dimethoxytritylDNB di(p-methoxyphenyl)phenylmethyl or dimeth

10、oxytritylDNMBS p,p-dinitrobenzhydrylDNP 4-(4,8-dimethoxynaphthylmethyl)benzenesulfonylDnpe 2,4-dinitrophenylDnpeoc 2-(2,4-dinitrophenyl)ethylDNs 2-(2,4-dinitrophenyl)ethoxycarbonylDnseoc 2,4-dinitrobenzenesulfonylDobz 2-dansylethoxycarbonylDoc p-(dihydroxyboryl)benzyloxycarbonylDOPS 2,4-dimethylpent

11、-3-yloxycarbonylDPA dimethyl1,1-dimethyl-3-(tetrahydro-2H-pyran-2-yloxy)propylsilylDPIPS diphenylacetylDPM or Dpm diphenylisopropylsilyl/diphenylmethylDPMS diphenylmethylsilylDpp diphenylphosphinylDppe 2-(diphenylphosphino)ethylDppm (diphenyl-4-pyridyl)methylDPSE 2-(methyldiphenylsilyl)ethylDpt diph

12、enylphosphinothioylDPTBS diphenyl-t-butoxysilyl or diphenyl-t-butylsilylDTBMS di-t-butylmethylsilylDTBS di-t-butylsilyleneDTE 2-(hydroxyethyl)dithioethyl or “dithiodiethanol”Dts dithiasuccinimidylEE 1-ethoxyethylEOM ethoxymethylFcm ferrocenylmethylFm 9-fluorenylmethylFmoc 9-fluorenylmethoxycarbonylG

13、UM guaiacolmethylHBn 2-hydroxybenzylHIP 1,1,1,3,3,3-hexafluoro-2-phenylisopropylHoc cyclohexyloxycarbonyl HSDIS (hydroxystyryl)diisopropylsilylHSDMS (hydroxystyryl)dimethylsilylhZ or homo 2 homobenzyloxycarbonyl/homobenzyloxycarbonylIDTr 3-(imidazol-1-ylmethyl)-4,4-dimethoxytriphenylmethylIETr 4,4-d

14、imethoxy-3-N-(imidazolylethyl)carbamoyltrityliMds 2,6-dimethoxy-4-methylbenzenesulfonylIpaoc 1-isopropylallyloxycarbonylIpc isopinocamphenylIPDMS isopropyldimethylsilylLev levulinoylLevS 4,4-(ethylenedithio)pentanoylLevS levulinoyldithioacetal ester2006-3-9 20:26:00 1楼：RE:保护基缩略语、全名大全MAQ 2-(9,10-anth

15、raquinonyl)methyl or 2-methyleneanthraquinoneMBE 1-methyl-1-benzyloxyethylMBF 2,3,3a,4,5,6,7,7a-octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-ylMBS or Mbs p-methoxybenzenesulfonylMds 2,6-dimethyl-4-methoxybenzenesulfonylMEC alpha-methylcinnamylMEM 2-methoxyethoxymethylMenpoc alpha-methylnitropip

16、eronyloxycarbonylMeOZ or Moz p-methoxybenzyloxycarbonylMes mesityl or 2,4,6-trimethylphenylMIP methoxyisopropyl or 1-methyl-1-methoxyethylMM menthoxymethylMMT or MMTr p-methoxyphenyldiphenylmethylMMTr or MMT p-methoxyphenyldiphenylmethylMOM methoxymethylMOMO methoxymethoxyMoz or Meoz p-methoxybenzyl

17、oxycarbonylMP p-methoxyphenylMPM or PMB p-methoxyphenylmethyl or p-methoxybenzylMps p-methoxyphenylsulfonylMpt dimethylphosphinothioylMs methanesulfonyl or mesylMsib 4-(methylsulfinyl)benzylMsz 4-methylsulfinylbenzyloxycarbonylMtb 2,4,6-trimethoxybenzenesulfonylMte 2,3,5,6-tetramethyl-4-methoxybenze

18、nesulfonylMTHP 4-methoxytetrahydropyranylMTM methylthiomethylMTMB 4-(methylthiomethoxy)butyryl MTMECO 2-(methylthiomethoxy)ethoxycarbonylMTMT 2-(methylthiomethoxymethyl)benzoylMtpc 4-(methylthio)phenoxycarbonylMtr 2,3,6-trimethyl-4-methoxybenzenesulfonylMts 2,4,6-trimethylbenzenesulfonyl or mesityle

19、nesulfonylNBOM nitrobenzyloxymethylNe 2-nitroethylNoc 4-nitrocinnamyloxycarbonylNosyl or Ns 2- or 4-nitrobenzenesulfonylNpe or npe 2-(nitrophenyl)ethylNpeoc 2-(4-nitrophenyl)ethoxycarbonylNpes 2-(4-nitrophenyl)ethylsulfonylNPS or Nps 2-nitrophenylsulfenylNpSSPeoc 2-(2-nitrophenyl)dithio-1-phenyletho

20、xycarbonylNpys 3-nitro-2-pyridinesulfenylNs or Nosyl 2- or 4-nitrobenzenesulfonylNVOC or Nvoc 3,4-dimethoxy-6-nitrobenzyloxycarbonyl or 6-nitroveratryloxycarbonylOBO 2,6,7-trioxabicyclo2.2.2octylONB o-nitrobenzylPAB p-acylaminobenzylPACH 2-2-(benzyloxy)ethylbenzoylPACM 2-2-(4-methoxybenzyloxy)ethylb

21、enzoylPaloc 3-(3-pyridyl)allyloxycarbonyl or 3-(3-pyridyl)prop-2-enyloxycarbonylPbf 2,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfonylPeoc 2-phosphonioethoxycarbonylPeoc 2-(triphenylphosphonio)ethoxycarbonylPet 2-(2-pyridyl)ethylPf 9-phenylfluorenylPhamc phenylacetamidomethylPhenoc 4-methoxyphenacylo

22、xycarbonylPim phthalimidomethylPixyl or Px 9-(9-phenyl)xanthenylPMB or MPM p-methoxybenzyl or p-methoxyphenylmethylPMBM p-methoxybenzyloxymethylPmc 2,2,5,7,8-pentamethylchroman-6-sulfonylPme pentamethylbenzenesulfonylPMP p-methoxyphenylPMS p-methylbenzylsulfonylPNB p-nitrobenzylPNP p-nitrophenylPNPE

23、 2-(4-nitrophenyl)ethylPOM 4-pentenyloxymethylPOM pivaloyloxymethyl PP 2-phenyl-2-propylPpoc 2-triphenylphosphonioisopropoxycarbonylPPt diphenylthiophosphinylPSE 2-(phenylsulfonyl)ethylPsec 2-(phenylsulfonyl)ethoxycarbonylPTE 2-(4-nitrophenyl)thioethylPTM phenylthiomethylPv pivaloylPx or pixyl 9-(9-

24、phenyl)xanthenylPyet 1-(alpha-pyridyl)ethylPyoc 2-(2-or 4-pyridyl)ethoxycarbonylQm 2-quinolinylmethylSATE S-acetylthioethylScm S-carboxymethylsulfenylSEE 1-2-(trimethylsilyl)ethoxyethylSEM 2-(trimethylsilyl)ethoxymethylSES 2-(trimethylsilyl)ethanesulfonylSisyl tris( trimethylsilyl)silyl SMOM (phenyl

25、dimethylsilyl)methoxymethylSnm S-(N-methyl-N-phenylcarbamoyl)sulfenylSTABASE 1,1,4,4-tetramethyldisilylazacyclopentaneTacm trimethylacetamidomethylTBDMS or TBS t-butyldimethylsilylTBDPS t-butyldiphenylsilylTbf-DMTr 4-(17-tetrabenzoa,c,g,ifluorenylmethyl-4,4-dimethoxytritylTbfmoc 17-tetrabenzoa,c,g,i

26、fluorenylmethoxycarbonylTBDS tetra-t-butoxydisiloxane-1,3-diylideneTBMPS t-butylmethoxyphenylsilylTBS or TBDMS t-butyldimethylsilylTBTr 4,4,4-tris(benzyloxy)triphenylmethylTCB 2,2,2-trichloro-1,1-dimethylethylTcBOC 1,1-dimethyl-2,2,2-trichloroethoxycarbonylTCP N-tetrachlorophthalimidoTcroc 2-(triflu

27、oromethyl)-6-chromonylmethyleneoxycarbonylTcrom 2-(trifluoromethyl)-6-chromonylmethyleneTDE (2,2,2-trifluoro-1,1-diphenyl)ethylTDS thexyldimethylsilylTeoc 2-(trimethylsilyl)ethoxycarbonylTES triethylsilylTf trifluoromethanesulfonylTFA trifluoroacetylTfav 4,4,4-trifluoro-3-oxo-1-butenylThexyl 2,3-dim

28、ethyl-2-butylTHF tetrahydrofuranyl THP tetrahydropyranylTIBS triisobutylsilyl TIPDS 1,3-(1,1,3,3-tetraisopropyldisiloxanylidene)TIPS triisopropylsilylTLTr 4,4,4-tris(levulinoyloxy)triphenylmethylTmb 2,4,6-trimethylbenzylTmob trimethoxybenzylTMPM trimethoxyphenylmethylTMS trimethylsilylTMSE or TSE 2-

29、(trimethylsilyl)ethylTMSEC 2-(trimethylsilyl)ethoxycarbonylTMSP 2-trimethylsilylprop-2-enylTMTr tris(p-methoxyphenyl)methylTos or Ts p-toluenesulfonylTPS triphenylsilylTPTE 2-(4-triphenylmethylthio)ethylTr triphenylmethyl or tritylTritylone 9-(9-phenyl-10-oxo)anthrylTroc 2,2,2-trichloroethoxycarbonylTs or Tos p-toluenesulfonylTSE or TMSE 2-(trimethylsilyl)ethylTse 2-(p-toluenesulfonyl)ethylVoc vinyloxycarbonylZ or Cbz benzyloxycarbonyl