100种有机溶剂的极性和其他物理常数列表.docx

100种有机溶剂的极性和其他物理常数列表.docx

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100种有机溶剂的极性和其他物理常数列表

100种有机溶剂的极性和其他物理常数列表

pp.408-411Appendix

TableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingENo.

（1）

（2）（3）（4）（5）（6）（7）（8）（9）SolventNameWaterFormamide1,2-EthanediolMethanolN-MethylformamideDiethyleneglycolTriethyIeneglycol2-MethoxyethanolTetraethyleneglycolNameinChinese水甲酰胺乙二醇甲醇甲基甲酰胺双乙二醇三乙二醇2-甲氧基乙醇四乙二醇甲基乙酰胺乙醇氨基乙醇乙酸丙醇苄醇丁醇戊醇异戊醇异丁醇异丙醇2-丁醇环己醇碳酸丙二酯2-戊醇硝基甲烷3-戊醇乙腈二甲亚砜苯胺环丁砜乙酸酐二甲基甲酰胺ET（h）10.7990.790.7620.7220.7130.7040.6670.6640.6570.6540.6510.6480.6170.6080.6020.5680.5650.5520.5460.5060.50.4910.4880.4810.4630.460.4440.420.410.4070.404bp（°C）100210.5197.564.5180-185245.7288124.6327.3206.778.3170.95117.997.15205.45117.7138130.5107.982.299.5161.1241.7119101.2115.381.6189184.4287.3（dec.）140153

（10）N-Methylacetamide（11）Ethanol（12）2-Aminoethanol（13）Aceticacid（14）1-Propanol（15）Benzylalcohol（16）1-Butanol（17）1-Pentanol（18）3-Methyl-1-butanol,Isoamylalcohol（19）2-Methyl-1-propanol,Isobutylalcohol（20）2-Propanolm）（21）2-Butanol（22）Cyclohexanol（23）Propylenecarbonate（24）2-Pentanol（25）Nitromethane（26）3-Pentanol（27）Acetonitrile（28）Dimethylsulfoxide（29）Aniline（30）SulfoIane（31）Aceticanhydride（32）N,N-Dimethyl-formamide

pp.408-411Appendix

TableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingE

（33）N,N-Dimethyl-acetamide（34）Propanenitrile（35）2-Methyl-2-propanol,t-Butanol（36）1.3-Dimethyl-imidazolidin-2-one,DMEU（37）1-Methylpyrrolidin-2-one（38）Acetone（39）1.3-Dimethyl-2-oxo-hexahydropyrimidine,DMPU（40）1,2-Diaminoethane（41）Cyanobenzene（42）1,2-Dichloroethane（43）2-Butanone（44）Nitrobenzene（45）2-Methyl-2-butanol,t-Pentylalcohol（46）2-Pentanone（47）Tetramethylurea（48）Morpholine（49）Hexamethylphosphoricacidtriamide,HMPT（50）3-Methyl-2-butanone（51）Dichloromethane“（52）Acetophenone（53）Pyridine（54）Methylacetate（55）Cyclohexanone（56）4-Methyl-2-pentanone（57）1,1-Dichloroethane（58）Quinoline（59）3-Pentanone（60）Chloroform（61）3,3-Dimethyl-2-butanone（62）Triethyleneglycoldimethylether（63）2,4-Dimethyl-3-pentanone（64）Diethyleneglycoldimethylether（65）1,2-Dimethoxyethane（66）Ethylacetate（67）1,2-Dichlorobenzene（68）2,6-Dimethyl-4-heptanone（69）Diethyleneglycoldiethylether

二甲基乙酰胺丙腈叔丁醇二甲基乙撑脲甲基砒咯烷酮丙酮二甲基亚丙基脲乙二胺腈基苯1,2-二氯乙烷丁酮,甲乙酮硝基苯叔戊醇2-戊酮四甲基脲吗啉六甲基磷酰胺异戊酮二氯甲烷苯乙酮吡啶乙酸甲酯环己酮4-甲基-2-戊酮1,1-二氯乙烷喹啉3-戊酮氯仿3,3-二甲基-2-丁酮三乙二醇二甲基醚2,4-二甲基-3-戊酮双乙二醇二甲基醚乙二醇二甲基醚乙酸乙酯邻二氯苯2,6-二甲基-4-

庚酮双乙二醇二乙基醚

0.4010.4010.3890.3640.3550.3550.3520.3490.3330.3270.3270.3240.3210.3210.3180.3180.3150.3150.3090.3060.3020.2870.2810.2690.2690.2690.2650.2590.2560.2530.2470.2440.2310.2280.2250.2250.21

166.197.3582.3225.520256.1230116.9191.183.579.6210.8102102.3175.2128.923394.239.6202115.2556.9155.65117.4573237.110261.2106.3216125.25159.8（dec.）84.577.1180.5168.2188.9

（70）Tetrahydrofuran（71）Methoxybenzene（72）Diethylcarbonate（73）Fluorobenzene（74）1,1-Dichloroethene（75）Chlorobenzene（76）Bromobenzene（77）Ethoxybenzene（78）lodobenzene（79）1,1,1-Trichloroethane（80）1,4-Dioxane（81）Trichloroethene（82）t-Butylmethylether（83）Piperidine（84）Diethylamine（85）Diphenylether（86）Diethylether（87）Benzene（88）Di-n-propylether（89）Toluene（90）1,4-Dimethylbenzene（91）Di-n-butylether（92）Carbondisulfide（93）Tetrachloromethane（94）Triethylamine（95）Tri-n-butylamine（96）cis-Decahydro-naphthaline（97）n-Heptane（98）n-Hexane（99）n-Pentane（100）Cyclohexane

四氢呋喃苯甲醚碳酸二乙酯氟苯1,1-二氯乙烯氯苯溴苯苯乙醚碘苯1,1,1-三氯乙烷二f烷三氯乙烯叔丁基甲醚哌啶二乙基胺二苯醚乙醚苯二丙醚甲苯对二甲苯二丁醚二硫化碳四氯甲烷三乙基胺三丁基胺顺十氢萘正庚烷正己烷正戊烷环己烷

0.2070.1980.1941940.1940.1880.1820.1820.170.170.1640.160.1480.1480.1450.1420.1170.1110.1020.0990.0740.0710.0650.0520.0430.0430.0150.0120.0090.0090.006

66153.6126.884.731.6131.7155.9169.8188.374.1101.387.255.2106.255.55258.134480190.1110.6138.4140.346.276.688.9214195.898.468.736.180.7

aThephysicalconstantsweretakenfromthefollowingreferences:

（1）R.C.WeastandM.J.Astle:

CRCHandbookofDataocMeltingpoint.dBoilingpointat1013mbar.eRelativepermittivity（dielectricconstant）forthepureliquidat25°Cunlessfollowedbyanothertemperatureinparentheses.

bC.ReichardtandE.Harbusch-G°rnert.LiebigsAnn.Chem1983,721;C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,B

aThephysicalconstantsweretakenfromthefollowingreferences:

（1）R.C.WeastandM.J.Astle:

CRCHa

cMeltingpoint.

dBoilingpointat1013mbar.

eRelativepermittivity（dielectricconstant）forthepureliquidat25°Cunlessfollowedbyanothertemperatureinparentheses.bC.ReichardtandE.Harbusch-G°rnert.LiebigsAnn.Chem1983,721;C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,B

fDipolemomentinCoulombmeter（10^（-30）Cm）.measuredinbenzene,tetrachloromethane,1,4-dioxane.O

hNormalisedET-values,derivedfromthetransitionenergyat25°Cofthelong-wavelengthabsorptionofas

IY.MarcusandS.Glikberg,PureAppl.Chem.57.855（1985）（Methanol）.

lY.Marcus,PureAppl.Chem.57,860（1985）（Ethanol）

mY.Marcus,PureAppl.Chem.58,1411（1986）（1-Propanol,2-Propanol,1-Butanol）.

nJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1541（1986）（Nitromethane）.

pM.Breant,Bull.Soc.Chim.Fr.197/,725（I-Methylpyrrolidin-2-one）.

qJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1535（1986）（Acetone）.

rC.Agarni,Bull.Soc.Chim.Fr./968,1205（1,2-Dimethoxyethane）.

sJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.57,633（1985）（THF,1,4-Dioxane）.gRefractiveindexattheaverageD-lineofsodium（*****cm-1）at20°CunlessfollowedbyanothertemperatureinparenthesekJ.F.Coetzee（ed.）:

RecommendedMethodsforPurificationofSolventsandTestsforImpurities（Acetonitrile,Sulfolane.ProoB.J.Barker,J.Rosenfarb,andJ.A.Caruso,Angew.Chem.91,560（1979）;Angew.Chem.,Int.Ed.Engl.18,503（1979）（D

tK.M.KadishandJ.E.Anderson,PureAppl.Chem.59,703（1987）（Benzonitrile,Dichloromethane.1,1-Dichloroethane,1,2-D

nstants,arrangedbydecreasingET-valuesasempiricalparameterofsolventpolarity.mp（°C）02.55-12.6-97.7-3.8-7.8-4.3-85.1-6.230.6-114.510.516.7-126.2-15.3-88.6-78.2-117.2-108-88-114.725.15-54.5-28.55-75-43.818.5-628.45-73.1-60.4nD20（g）1.3331.44751.43181.32841.43191.44751.45581.40211.45771.4253（35°）1.3614*****1.37191.38561.54041.39931.411.40721.39591.37721.39711.4648（25°）1.42151.40641.38191.41041.34411.47931.58631.4816（30°）1.39041.4305Er（e）78.3111.0（20°）37.732.66182.431.69（20°）23.69（20°）16.9319.7191.3（32°）24.5537.726.17（20°）20.4513.1（20°）17.5113.915.1917.9319.9216.561564.9213.7135.9413.3535.9446.456.71（30°）43.3（30°）20.7（19°）36.71u（f）5.911.27.75.712.97.710.06.810.814.25.87.65.65.55.55.85.76.16.05.55.56.216.55.511.95.511.813.55.0169.410.8

angedbydecreasingET-valuesasempiricalparameterofsolventpolarity.

-20-92.825.68.2-24.4-94.7-2011.3-12.75-35.7-86.75.8-8.8-76.9-1.2-4.87.2-92-94.919.6-41.55-98.05-32.1-84.7-97-14.85-39-63.5-49.8-45-69-64-69-83.55-17-46-44.3

1.43841.36581.38771.4707（25°）1.471.35871.4881（25°）1.45681.52821.44481.37881.55621.4051.39081.4493（25°）1.4542*****1.3881.42421.53421.51021.36141.4511.39581.41641.62731.39231.44591.39521.42241.39991.40781.37961.37241.55151.41221.4115

37.7828.86（20°）12.4737.632.220.5636.1212.925.210.3718.51（20°）34.785.7815.38（20°）23.67.4229615.87（30°）8.9317.3912.916.6816.10（20°）13.11（20°）10.0（18°）8.9517.00（20°）4.81（20°）13.1（14.5°）7.517.2（20°）5.87.26.029.939.91（20°）5.7

12.411.75.513.613.69.014.16.313.46.19.2133.05.790.011.75.218.59.25.29.87.95.710.32.76.17.39.43.89.39.16.65.76.17.18.9

-108.4-37.5-43-42.2-122.6-45.6-30.8-29.5-31.35-30.411.8-86.4-108.6-10.5-49.826.9-116.35.5-123.2-9513.3-95.2-111.6-22.8-114.7-70-43-90.6-95.3-129.76.7

1.40721.5171.38371.4684（15°）1.42471.52481.55681.50741.621.4381.42241.47731.3691.45251.38461.5763（30°）1.35241.50111.38051.49691.49581.39921.627514,6021.4011.42911.4811.38761.37491.35751.4262

7.584.332.82（20°）5.424.82（20°）5.625.44.22（20°）4.49（20°）7.25（20°）2.213.42（16°）4.5（20°）5.8（20°）3.783.69（20°）4.22.273.39（26°）2.382.27（20°）3.08（20°）2.64（20°）2.232.42（20°）2.20（20°）

1.92（20°）1.881.84（20°）2.02（20°）

5.84.23.04.94.35.45.24.54.75.71.52.74.14.04.03.93.80.04.41.00.03.90.00.02.92.60.00.00.00.00.0

J.Astle:

CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;

（2）RC.Weast（ed.）:

Handbooko

olet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:

ibid.1987,1001;cf.alsoTable7-3inChapter7.

hertemperatureinparentheses.

J.Astle:

CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;

（2）RC.Weast（ed.）:

Handbookoolet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:

ibid.1987,1001;cf.alsoTable7-3inChapter7.

hertemperatureinparentheses.

e,1,4-dioxane.Orn-hexaneat20-30°C.1Debye=3.336x10-30Cm.

ofastandardpyridinium-N-phenoxidebetainedye,ET（30）;cf.Eqs.（7-27）and（7-29）inSection7.4

tonitrile,Sulfolane.Propylenecarbonate,Dimethylsulfoxide,N,N-Dimethylformamide,Hexamethylphosphorictriamanothertemperatureinparentheses.

m.,Int.Ed.Engl