种有机溶剂的极性和其他物理常数列表表格文件下载.xls

种有机溶剂的极性和其他物理常数列表表格文件下载.xls

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CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;

（2）RC.Weast（ed.）:

HandbookofChemistryandPhysics,66thedition.CRCPress,BocaRaton/Florida1985/86;

（3）J.A.Riddick,W.B.Bunger,andT.K.Sakano:

OrganicSolvents.PhysicalPropertiesandMethodrofPurification.4thedition.InA.Weissberger（ed.）:

TechniquesofChemistry,Vol.II,Wiley-lnterscience,NewYork1986:

（4）A.L.McClellan:

TablesofExperimentalDipoleMoments.Freeman.SanFrancisco.London1963;

（5）A.A.MaryottandE.R.Smith:

TableofDielectricConstantsofPureLiquids.NBSCircular514;

Washington1951;

（6）DeilsteinsHandbookofOrganicChemistry.Springer-Verlag,Berlin;

（7）M.Windholz（ed.）:

TheMerckIndex.10thedition,Rahway/NewJersey1983.bC.ReichardtandE.Harbusch-Grnert.LiebigsAnn.Chem1983,721;

C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:

ibid.1987,1001;

cf.alsoTable7-3inChapter7.cMeltingpoint.dBoilingpointat1013mbar.eRelativepermittivity（dielectricconstant）forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter（10（-30）Cm）.measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium（16969cm-1）at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET（30）;

cf.Eqs.（7-27）and（7-29）inSection7.4IY.MarcusandS.Glikberg,PureAppl.Chem.57.855（1985）（Methanol）.kJ.F.Coetzee（ed.）:

RecommendedMethodsforPurificationofSolventsandTestsforImpurities（Acetonitrile,Sulfolane.Propylenecarbonate,Dimethylsulfoxide,N,N-Dimethylformamide,Hexamethylphosphorictriamide,Pyridine,1.2-Diaminoethane,N-Methylacetamide,andN-Methylpropionamide）.PergamonPress,Oxford1982.lY.Marcus,PureAppl.Chem.57,860（1985）（Ethanol）mY.Marcus,PureAppl.Chem.58,1411（1986）（1-Propanol,2-Propanol,1-Butanol）.nJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1541（1986）（Nitromethane）.oB.J.Barker,J.Rosenfarb,andJ.A.Caruso,Angew.Chem.91,560（1979）;

Angew.Chem.,Int.Ed.Engl.18,503（1979）（DMEU,DMPU,Tetramethylurea）.pM.Breant,Bull.Soc.Chim.Fr.197/,725（I-Methylpyrrolidin-2-one）.qJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1535（1986）（Acetone）.rC.Agarni,Bull.Soc.Chim.Fr./968,1205（1,2-Dimethoxyethane）.sJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.57,633（1985）（THF,1,4-Dioxane）.tK.M.KadishandJ.E.Anderson,PureAppl.Chem.59,703（1987）（Benzonitrile,Dichloromethane.1,1-Dichloroethane,1,2-Dichloroethane）.mp（C）nD20（g）Er（e）u（f）01.33378.35.92.551.4475111.0（20）11.2-12.61.431837.77.7-97.71.328432.665.7-3.81.4319182.412.9-7.81.447531.69（20）7.7-4.31.455823.69（20）10.0-85.11.402116.936.8-6.21.457719.710.830.61.4253（35）191.3（32）14.2-114.51.361424.555.810.51454537.727.616.71.37196.17（20）5.6-126.21.385620.455.5-15.31.540413.1（20）5.5-88.61.399317.515.8-78.21.4113.95.7-117.21.407215.196.1-1081.395917.936.0-881.377219.925.5-114.71.397116.565.525.151.4648（25）156.2-54.51.421564.9216.51.406413.715.5-28.551.381935.9411.9-751.410413.355.5-43.81.344135.9411.818.51.479346.4513.5-61.58636.71（30）5.028.451.4816（30）43.3（30）16-73.11.390420.7（19）9.4-60.41.430536.7110.8-201.438437.7812.4TableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingET-valuesasempiricalparameterofsolventpolarity.-92.81.365828.86（20）11.725.61.387712.475.58.21.4707（25）37.613.6-24.41.4732.213.6-94.71.358720.569.0-201.4881（25）36.1214.111.31.456812.96.3-12.751.528225.213.4-35.71.444810.376.1-86.71.378818.51（20）9.25.81.556234.78133.0-8.81.4055.785.7-76.91.390815.38（20）90.0-1.21.4493（25）23.611.7-4.81.45427.425.27.21458829618.5-921.38815.87（30）9.2-94.91.42428.935.219.61.534217.399.8-41.551.510212.917.9-98.051.36146.685.7-32.11.45116.10（20）10.3-84.71.395813.11（20）2.7-971.416410.0（18）6.1-14.851.62738.957.3-391.392317.00（20）9.4-63.51.44594.81（20）3.8-49.81.395213.1（14.5）9.3-451.42247.5-691.399917.2（20）9.1-641.40785.86.6-691.37967.25.7-83.551.37246.026.1-171.55159.937.1-461.41229.91（20）8.9-44.31.41155.7-108.41.40727.585.8-37.51.5174.334.2-431.38372.82（20）3.0-42.21.4684（15）5.424.9-122.61.42474.82（20）4.3-45.61.52485.625.4-30.81.55685.45.2-29.51.50744.22（20）4.5-31.351.624.49（20）4.7-30.41.4387.25（20）5.711.81.42242.211.5-86.41.47733.42（16）2.7-108.61.3694.5（20）4.1-10.51.45255.8（20）4.0-49.81.38463.784.026.91.5763（30）3.69（20）3.9-116.31.35244.23.85.51.50112.270.0-123.21.38053.39（26）4.4-951.49692.381.013.31.49582.27（20）0.0-95.21.39923.08（20）3.9-111.61.62752.64（20）0.0-22.814,6022.230.0-114.71.4012.42（20）2.9-701.4291-2.6-431.4812.20（20）0.0-90.61.38761.92（20）0.0-95.31.37491.880.0-129.71.35751.84（20）0.06.71.42622.02（20）0.0aThephysicalconstantsweretakenfromthefollowingreferences:

cf.alsoTable7-3inChapter7.eRelativepermittivity（dielectricconstant）forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter（10（-30）Cm）.measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium（16969cm-1）at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET（30）;

cf.Eqs.（7-27）and（7-29）