种有机溶剂的极性和其他物理常数列表.xls

种有机溶剂的极性和其他物理常数列表.xls

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pp.408-411AppendixTableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingET-valuesasempiricalparameterofsolventpolarity.No.SolventNameNameinChineseET（h）bp（C）

（1）Water水1100

（2）Formamide甲酰胺0.799210.5（3）1,2-Ethanediol乙二醇0.79197.5（4）Methanol甲醇0.76264.5（5）N-Methylformamide甲基甲酰胺0.722180-185（6）Diethyleneglycol双乙二醇0.713245.7（7）TriethyIeneglycol三乙二醇0.704288（8）2-Methoxyethanol2-甲氧基乙醇0.667124.6（9）Tetraethyleneglycol四乙二醇0.664327.3（10）N-Methylacetamide甲基乙酰胺0.657206.7（11）Ethanol乙醇0.65478.3（12）2-Aminoethanol氨基乙醇0.651170.95（13）Aceticacid乙酸0.648117.9（14）1-Propanol丙醇0.61797.15（15）Benzylalcohol苄醇0.608205.45（16）1-Butanol丁醇0.602117.7（17）1-Pentanol戊醇0.568138（18）3-Methyl-1-butanol,Isoamylalcohol异戊醇0.565130.5（19）2-Methyl-1-propanol,Isobutylalcohol异丁醇0.552107.9（20）2-Propanolm）异丙醇0.54682.2（21）2-Butanol2-丁醇0.50699.5（22）Cyclohexanol环己醇0.5161.1（23）Propylenecarbonate碳酸丙二酯0.491241.7（24）2-Pentanol2-戊醇0.488119（25）Nitromethane硝基甲烷0.481101.2（26）3-Pentanol3-戊醇0.463115.3（27）Acetonitrile乙腈0.4681.6（28）Dimethylsulfoxide二甲亚砜0.444189（29）Aniline苯胺0.42184.4（30）SulfoIane环丁砜0.41287.3（dec.）（31）Aceticanhydride乙酸酐0.407140（32）N,N-Dimethyl-formamide二甲基甲酰胺0.404153（33）N,N-Dimethyl-acetamide二甲基乙酰胺0.401166.1（34）Propanenitrile丙腈0.40197.35（35）2-Methyl-2-propanol,t-Butanol叔丁醇0.38982.3（36）1.3-Dimethyl-imidazolidin-2-one,DMEU二甲基乙撑脲0.364225.5（37）1-Methylpyrrolidin-2-one甲基砒咯烷酮0.355202（38）Acetone丙酮0.35556.1（39）1.3-Dimethyl-2-oxo-hexahydropyrimidine,DMPU二甲基亚丙基脲0.352230（40）1,2-Diaminoethane乙二胺0.349116.9（41）Cyanobenzene腈基苯0.333191.1（42）1,2-Dichloroethane1,2-二氯乙烷0.32783.5（43）2-Butanone丁酮,甲乙酮0.32779.6（44）Nitrobenzene硝基苯0.324210.8（45）2-Methyl-2-butanol,t-Pentylalcohol叔戊醇0.321102（46）2-Pentanone2-戊酮0.321102.3（47）Tetramethylurea四甲基脲0.318175.2（48）Morpholine吗啉0.318128.9（49）Hexamethylphosphoricacidtriamide,HMPT六甲基磷酰胺0.315233（50）3-Methyl-2-butanone异戊酮0.31594.2（51）Dichloromethane二氯甲烷0.30939.6（52）Acetophenone苯乙酮0.306202（53）Pyridine吡啶0.302115.25（54）Methylacetate乙酸甲酯0.28756.9（55）Cyclohexanone环己酮0.281155.65（56）4-Methyl-2-pentanone4-甲基-2-戊酮0.269117.4（57）1,1-Dichloroethane1,1-二氯乙烷0.269573（58）Quinoline喹啉0.269237.1（59）3-Pentanone3-戊酮0.265102（60）Chloroform氯仿0.25961.2（61）3,3-Dimethyl-2-butanone3,3-二甲基-2-丁酮0.256106.3（62）Triethyleneglycoldimethylether三乙二醇二甲基醚0.253216（63）2,4-Dimethyl-3-pentanone2,4-二甲基-3-戊酮0.247125.25（64）Diethyleneglycoldimethylether双乙二醇二甲基醚0.244159.8（dec.）（65）1,2-Dimethoxyethane乙二醇二甲基醚0.23184.5（66）Ethylacetate乙酸乙酯0.22877.1（67）1,2-Dichlorobenzene邻二氯苯0.225180.5（68）2,6-Dimethyl-4-heptanone2,6-二甲基-4-庚酮0.225168.2（69）Diethyleneglycoldiethylether双乙二醇二乙基醚0.21188.9（70）Tetrahydrofuran四氢呋喃0.20766（71）Methoxybenzene苯甲醚0.198153.6（72）Diethylcarbonate碳酸二乙酯0.194126.8（73）Fluorobenzene氟苯19484.7（74）1,1-Dichloroethene1,1-二氯乙烯0.19431.6（75）Chlorobenzene氯苯0.188131.7（76）Bromobenzene溴苯0.182155.9（77）Ethoxybenzene苯乙醚0.182169.8（78）lodobenzene碘苯0.17188.3（79）1,1,1-Trichloroethane1,1,1-三氯乙烷0.1774.1（80）1,4-Dioxane二噁烷0.164101.3（81）Trichloroethene三氯乙烯0.1687.2（82）t-Butylmethylether叔丁基甲醚0.14855.2（83）Piperidine哌啶0.148106.2（84）Diethylamine二乙基胺0.14555.55（85）Diphenylether二苯醚0.142258.1（86）Diethylether乙醚0.117344（87）Benzene苯0.111801（88）Di-n-propylether二丙醚0.10290.1（89）Toluene甲苯0.099110.6（90）1,4-Dimethylbenzene对二甲苯0.074138.4（91）Di-n-butylether二丁醚0.071140.3（92）Carbondisulfide二硫化碳0.06546.2（93）Tetrachloromethane四氯甲烷0.05276.6（94）Triethylamine三乙基胺0.04388.9（95）Tri-n-butylamine三丁基胺0.043214（96）cis-Decahydro-naphthaline顺十氢萘0.015195.8（97）n-Heptane正庚烷0.01298.4（98）n-Hexane正己烷0.00968.7（99）n-Pentane正戊烷0.00936.1（100）Cyclohexane环己烷0.00680.7aThephysicalconstantsweretakenfromthefollowingreferences:

（1）R.C.WeastandM.J.Astle:

CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;

（2）RC.Weast（ed.）:

HandbookofChemistryandPhysics,66thedition.CRCPress,BocaRaton/Florida1985/86;（3）J.A.Riddick,W.B.Bunger,andT.K.Sakano:

OrganicSolvents.PhysicalPropertiesandMethodrofPurification.4thedition.InA.Weissberger（ed.）:

TechniquesofChemistry,Vol.II,Wiley-lnterscience,NewYork1986:

（4）A.L.McClellan:

TablesofExperimentalDipoleMoments.Freeman.SanFrancisco.London1963;（5）A.A.MaryottandE.R.Smith:

TableofDielectricConstantsofPureLiquids.NBSCircular514;Washington1951;（6）DeilsteinsHandbookofOrganicChemistry.Springer-Verlag,Berlin;（7）M.Windholz（ed.）:

TheMerckIndex.10thedition,Rahway/NewJersey1983.bC.ReichardtandE.Harbusch-Grnert.LiebigsAnn.Chem1983,721;C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:

ibid.1987,1001;cf.alsoTable7-3inChapter7.cMeltingpoint.dBoilingpointat1013mbar.eRelativepermittivity（dielectricconstant）forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter（10（-30）Cm）.measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium（16969cm-1）at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET（30）;cf.Eqs.（7-27）and（7-29）inSection7.4IY.MarcusandS.Glikberg,PureAppl.Chem.57.855（1985）（Methanol）.kJ.F.Coetzee（ed.）:

RecommendedMethodsforPurificationofSolventsandTestsforImpurities（Acetonitrile,Sulfolane.Propylenecarbonate,Dimethylsulfoxide,N,N-Dimethylformamide,Hexamethylphosphorictriamide,Pyridine,1.2-Diaminoethane,N-Methylacetamide,andN-Methylpropionamide）.PergamonPress,Oxford1982.lY.Marcus,PureAppl.Chem.57,860（1985）（Ethanol）mY.Marcus,PureAppl.Chem.58,1411（1986）（1-Propanol,2-Propanol,1-Butanol）.nJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1541（1986）（Nitromethane）.oB.J.Barker,J.Rosenfarb,andJ.A.Caruso,Angew.Chem.91,560（1979）;Angew.Chem.,Int.Ed.Engl.18,503（1979）（DMEU,DMPU,Tetramethylurea）.pM.Breant,Bull.Soc.Chim.Fr.197/,725（I-Methylpyrrolidin-2-one）.qJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1535（1986）（Acetone）.rC.Agarni,Bull.Soc.Chim.Fr./968,1205（1,2-Dimethoxyethane）.sJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.57,633（1985）（THF,1,4-Dioxane）.tK.M.KadishandJ.E.Anderson,PureAppl.Chem.59,703（1987）（Benzonitrile,Dichloromethane.1,1-Dichloroethane,1,2-Dichloroethane）.mp（C）nD20（g）Er（e）u（f）01.33378.35.92.551.4475111.0（20）11.2-12.61.431837.77.7-97.71.328432.665.7-3.81.4319182.412.9-7.81.447531.69（20）7.7-4.31.455823.69（20）10.0-85.11.402116.936.8-6.21.457719.710.830.61.4253（35）191.3（32）14.2-114.51.361424.555.810.51454537.727.616.71.37196.17（20）5.6-126.21.385620.455.5-15.31.540413.1（20）5.5-88.61.399317.515.8-78.21.4113.95.7-117.21.407215.196.1-1081.395917.936.0-881.377219.925.5-114.71.397116.565.525.151.4648（25）156.2-54.51.421564.9216.51.406413.715.5-28.551.381935.9411.9-751.410413.355.5-43.81.344135.9411.818.51.479346.4513.5-61.58636.71（30）5.028.451.4816（30）43.3（30）16-73.11.390420.7（19）9.4-60.41.430536.7110.8-201.438437.7812.4TableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingET-valuesasempiricalparameterofsolventpolarity.-92.81.365828.86（20）11.725.61.387712.475.58.21.4707（25）37.613.6-24.41.4732.213.6-94.71.358720.569.0-201.4881（25）36.1214.111.31.456812.96.3-12.751.528225.213.4-35.71.444810.376.1-86.71.378818.51（20）9.25.81.556234.78133.0-8.81.4055.785.7-76.91.390815.38（20）90.0-1.21.4493（25）23.611.7-4.81.45427.425.27.21458829618.5-921.38815.87（30）9.2-94.91.42428.935.219.61.534217.399.8-41.551.510212.917.9-98.051.36146.685.7-32.11.45116.10（20）10.3-84.71.395813.11（20）2.7-971.416410.0（18）6.1-14.851.62738.957.3-391.392317.00（20）9.4-63.51.44594.81（20）3.8-49.81.395213.1（14.5）9.3-451.42247.5-691.399917.2（20）9.1-641.40785.86.6-691.37967.25.7-83.551.37246.026.1-171.55159.937.1-461.41229.91（20）8.9-44.31.41155.7-108.41.40727.585.8-37.51.5174.334.2-431.38372.82（20）3.0-42.21.4684（15）5.424.9-122.61.42474.82（20）4.3-45.61.52485.625.4-30.81.55685.45.2-29.51.50744.22（20）4.5-31.351.624.49（20）4.7-30.41.4387.25（20）5.711.81.42242.211.5-86.41.47733.42（16）2.7-108.61.3694.5（20）4.1-10.51.45255.8（20）4.0-49.81.38463.784.026.91.5763（30）3.69（20）3.9-116.31.35244.23.85.51.50112.270.0-123.21.38053.39（26）4.4-951.49692.381.013.31.49582.27（20）0.0-95.21.39923.08（20）3.9-111.61.62752.64（20）0.0-22.814,6022.230.0-114.71.4012.42（20）2.9-701.4291-2.6-431.4812.20（20）0.0-90.61.38761.92（20）0.0-95.31.37491.880.0-129.71.35751.84（20）0.06.71.42622.02（20）0.0aThephysicalconstantsweretakenfromthefollowingreferences:

（1）R.C.WeastandM.J.Astle:

CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;

（2）RC.Weast（ed.）:

HandbookofChemistryandPhysics,66thedition.CRCPress,BocaRaton/Florida1985/86;（3）J.A.Riddick,W.B.Bunger,andT.K.Sakano:

OrganicSolvents.PhysicalPropertiesandMethodrofPurification.4thedition.InA.Weissberger（ed.）:

TechniquesofChemistry,Vol.II,Wiley-lnterscience,NewYork1986:

（4）A.L.McClellan:

TablesofExperimentalDipoleMoments.Freeman.SanFrancisco.London1963;（5）A.A.MaryottandE.R.Smith:

TableofDielectricConstantsofPureLiquids.NBSCircular514;Washington1951;（6）DeilsteinsHandbookofOrganicChemistry.Springer-Verlag,Berlin;（7）M.Windholz（ed.）:

TheMerckIndex.10thedition,Rahway/NewJersey1983.bC.ReichardtandE.Harbusch-Grnert.LiebigsAnn.Chem1983,721;C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:

ibid.1987,1001;cf.alsoTable7-3inChapter7.eRelativepermittivity（dielectricconstant）forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter（10（-30）Cm）.measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium（16969cm-1）at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET（30）;cf.Eqs.（7-27）and（7-29）